You can attach any type of file to your e-mail message by setting options as shown in the following code. The following code attaches the active spreadsheet's left-most Sheet content as PDF.
function sendEmailWithAttachments(){ var file = SpreadsheetApp.getActiveSpreadsheet() .getAs(MimeType.PDF); // MailApp.sendEmail(recipient, subject, body, options) MailApp.sendEmail( "[[ Recipient email id ]]", "Chapter 3", "", { attachments: [file], name: 'Chapter 3 test attachment' } ); }